After opening up Outlook Express, browse to Tools -> Accounts:
Next, select your mail account from the list and click the "Properties" button at right (if you are creating a new account click the "Add" button, followed by "Mail"):
Next you'll see the screen below. These fields may already be filled in (in which case you can leave them). If not, enter a name for your mail account in the first box, followed by your name, organization's name, and email address:

2. Incoming Mail Server:
3. Outgoing Mail Server:
Check the box that says "My server requires authentication" and then click the "Settings..." button. This will bring you to the following screen:
Select "Use same settings as my incoming mail server" and click "OK." Click "OK" at the next window as well, and "Close" on the last window to save your changes.
Voila :) Pat yourself on the back for a job well done! You can now send and receive emails as normal.
FYI - anytime you are on the road or are having Outlook Express troubles, you may always check your email directly on the server by visiting example.com/webmail (replace with your website name). You will be asked for your username and password. These are your full email address (name@example.com) and your email password.
Go back into your email account settings, but this time, instead of clicking on the "Outgoing Server" tab as above, click on the "Advanced" tab. Try changing the "Outgoing mail (SMTP)" port number to 26 (25 is the default):
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Thank you for keeping it simple
Thank you for keeping it simple for those of us who are not computer literate.
Glad to hear it
No problem - that's the whole purpose of this community site, especially when it comes to software like Outlook Express that should be "express" and easy to use. Comments like yours are uplifting, and let us know we're still on the right track. Thanks!